A Priori Assessment of the Stereoelectronic Profile of Phosphines and Phosphites
نویسندگان
چکیده
منابع مشابه
A priori assessment of the stereoelectronic profile of phosphines and phosphites.
This research has demonstrated the utility of a rigorously calibrated, molecular mechanics/semiempirical quantum mechanical protocol for developing stereoelectronic (Tolman) maps for phosphine ligands. A computational analysis of alkyl and aryl phosphines in common usage suggests that these ligands are quite similar stereoelectronically. A noticeable gap in the Tolman map for common phosphines ...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2003
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja021254i